Posts Tagged ‘investment in green chemistry’

Can Green Chemistry get us out of Deepwater?

Tuesday, July 27th, 2010

By Elizabeth Grossman and Karen Peabody O’Brien

It is now more than three months since the Deepwater Horizon rig exploded, killing 11 workers, injuring more, and unleashing its vast underwater oil gusher into the Gulf of Mexico. As this unnatural disaster continues with devastating consequences to Gulf Coast wetlands, wildlife, culture, and economy, our attention is – quite understandably – focused on the immediate. But as we hasten to rescue, repair, and restore, shouldn’t we also be thinking about what we can do to make sure this never happens again?

This question has many answers. Among them is green chemistry, the science that calls for eliminating hazards and waste at the design stage rather than at the end of the pipe – literally and figuratively. While not a magic wand, green chemistry would go a long way toward moving us away from society’s dependence on toxic petrochemicals as the basis for most manufactured materials.

Rather than preventing pollution and toxic exposures by designing products to be without inherent hazards, we’ve relied on containing, or “managing,” the risk of exposure. And risk management works… until it doesn’t. Sooner or later, it fails. Hence Bhopal. Hence toxic spills. Hence the Deepwater Horizon disaster. Accidents happen.

Historically, we’ve taken these risks and assumed the environment would successfully absorb the consequences of our industrial effluence – accidental or intentional. But clearly this is not working.

Green chemistry can change this course. It is a radical departure from the status quo, the age-old practice of valuing expedience at the expense of the environment and human health.

Green chemistry design has already created products like paint made with soy additives, pesticides made from microbes, and plastics made from orange peels. There are even green chemistry products that can break down petroleum in environmentally benign ways, products that detoxify hazardous petrochemicals and leave behind nothing more toxic than oxygen and water. Not only are these products safe for human health but who wouldn’t prefer an orange peel spill to what is happening in the Gulf?

So far, nearly 2 million gallons of chemical oil dispersants have been poured into the Gulf. Yet these EPA-approved dispersants – themselves petroleum-based products with unknown long term ecological and health impacts – are products of the kind of old thinking and outdated design that got us into this mess in the first place.

“This is an engineering miracle,” said Paul Anastas, assistant administrator for the Environmental Protection Agency’s Office of Research and Development, pointing to a photograph of the Deepwater Horizon drilling rig. “But when we define our goals, we define the consequences of our actions,” he continued in remarks to the 14th annual American Chemistry Society Green Chemistry and Engineering conference in Washington, DC, last month. “There is no doubt,” said Anastas who is also a founder of green chemistry, “that we’re on an unsustainable trajectory.”

To change this course, said Anastas, “we need to design into our technologies the consequences to human health and the environment.”

We have the capacity to do this – to create high performance products that are both effective and environmentally benign. But until we make a real commitment to this transformation we will be limited to what Anastas called “elegant and expensive technological bandages that are inherently unsustainable.”

What would such a commitment look like?

- Every chemistry PhD student would graduate with an in-depth understanding of the environmental costs and benefits of the design choices they make. Every chemistry student would learn the biological mechanisms of toxicology. Investing in and expanding green chemistry education is key. Equipping the next generation with the tools necessary to create sustainable technologies is essential.

- Government procurement programs would use green chemistry principles to seek out the ‘greenest’ technologies. Rather than being limited to products (ranging from dispersants to carpets) that fit a standard set decades ago, government agencies would be empowered to choose and use the most environmentally innovative.

- Companies would compete to lead the transition away from chemicals of greatest concern. We are not talking about using marginally “less bad” chemicals, but about redesigning products and processes to be inherently benign and sustainable. How much smarter is it to become a market leader rather than wait for regulations to force a change?

We don’t need rocket science to prevent future Deepwater disasters. We need chemistry. And green chemistry is one of our most promising tools. Let’s deploy it to its fullest potential.

Original article at The Huffington Post

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Cancer and green chemistry.

Tuesday, July 13th, 2010

The Boston Globe

Cancer and green chemistry

By Teresa Heinz Kerry, Terry Collins and John Warner July 10, 2010

THE PRESIDENT’S Cancer Panel recently issued a stunning report on the role of environmental factors in causing cancer. For those wondering why America has yet to win the war against cancer, the panel minces no words: “The true burden of environmentally induced cancers has been grossly underestimated.’’ If you ignore the cause, how can you prevent cancer and really win the war?

The panel urges strong actions to reduce people’s widespread exposures to carcinogens. It says the prevailing regulatory approach used in the United States is “reactionary, not preventive.’’ It concludes that US regulation of cancer-causing chemicals is ineffective for several reasons, including inadequate funding, weak laws, and undue industry influence.

This report is not the result of a liberal panel following the lead of the Obama administration. Both panel members were appointed by President George W. Bush and the panel’s public hearings were conducted before Bush left office.The report identifies a series of actions that can be taken to win the war against cancer.

First, it recommends that a prevention-oriented approach should replace the current reactionary system, and that this should become the cornerstone of a new national cancer prevention strategy.

It finds that government agencies responsible for protecting Americans from cancer need more tools, and that a more integrated and transparent system — one driven by science and free from political or industry influence — must be developed to protect public health.

Among its many recommendations, we were especially encouraged to find this: “ ‘Green chemistry’ initiatives and research . . . should be pursued and supported more aggressively. . .’’ Green chemistry offers a path forward that leads both to a healthier America and a wave of positive chemical innovations that can strengthen our economy.

World markets want safe materials. Green chemistry will be able to provide them, but only if it gets the resources it needs to flourish. Other countries, including Germany, India, and, China, are investing far more in green chemistry than the United States does. As demand grows for safer materials because of the compelling science that show how chemicals in wide use today are undermining our health, America’s chemical industry needs to become the leader.

What’s holding us back? Lack of financial support for green chemistry research and innovation. But just turning on the funding spigot won’t be enough. We also need to reinvent how chemistry is taught in US colleges and universities.

Green chemistry equips chemists with the knowledge to ask tough questions about potential hazards when they are thinking about making a new chemical. As they make choices early in new chemical design, this simple step could dramatically reduce the chances that new chemicals would be toxic.

In the past, chemists have rarely been trained to ask these questions. It’s as if a course in driver’s education never taught students about traffic accidents. Perhaps not surprisingly, students as well as potential employers are creating demand for this change.

Green chemistry has a long way to go to develop a full toolkit of chemical methods that can replace more classic approaches. But the path is clear, a “prevention-oriented’’ design strategy that can do honor to the President’s Cancer Panel’s insistence that “new products must be well-studied prior to and following their introduction into the environment. . .’’

Invigorating green chemistry is a win-win solution. Americans will become healthier because the materials in their homes, the air, and water will be safe by design, and the chemical industry will be better positioned to compete in world markets that care about chemical safety.

Teresa Heinz Kerry is chairman of the Heinz Family Philanthropies. Terry Collins is a professor of green chemistry at Carnegie Mellon University. John Warner is president of the Warner-Babcock Institute for Green Chemistry.

Oregon could become a Green Chemistry powerhouse.

Tuesday, July 6th, 2010

Group aims to make Oregon a green chemistry powerhouse

The Oregonian. Published: Thursday, July 01, 2010, 5:51 PM. Original article

Six years ago, Wilsonville-based Coastwide Laboratories introduced a line of cleaning supplies engineered to reduce toxic ingredients and break down into safe compounds after being used.

After a year on the market, the Sustainable Earth line made up 20 percent of Coastwide’s sales, while traditional cleaners made up the rest. Today, the environmentally friendly products make up 80 percent of sales for the company, a division of office supplies giant Staples Inc.

“Fundamentally the proof in the pudding is whether consumers buy the product and continue to buy the product, and what they make the decision to buy the product around,” said Roger McFadden, a vice president and senior scientist at Staples.

A group of Oregon business leaders and researchers have released a report on what Oregon should do to bolster its profile in so-called “green chemistry.” The report profiles Coastwide, Nike, Blount International and Columbia Forest Products, all companies that use green chemistry and are represented on the Oregon Green Chemistry Advisory Group.

To turn Oregon into a green chemistry powerhouse, the advisory group recommends focusing on public awareness and work-related education. Businesses and consumers need to know the advantages of green chemistry and educators need to train a workforce prepared to work in the field.

The report also proposes a hub, housed at an Oregon university, to coordinate green chemistry efforts and a state purchasing policy that gives preference to green products. It also recommends making state economic development funding available for green chemistry activities and creating incentives to mitigate the cost of adopting green chemistry.

The full report is posted on the Oregon Environmental Council’s website.

Green chemistry is based on a set of principles designed to promote environmentally sound production starting from the first design steps. The final products should be non-toxic and should break down into benign substances once they’ve been released into the environment.

The principles also promote efficiency, such as eliminating manufacturing chemicals that don’t make it into the final product and using renewable raw materials.

For the companies, that can mean more efficient production, better compliance with current and future regulation and the chance to pitch their products as the eco-friendly choice.

“Sustainability is integral to (companies’) long-term success, and increasingly they’re realizing that green chemistry is a great tool for overcoming some of their sustainability-related challenges,” said Colin Price, the research director for the Oregon Environmental Council. Price was a member of the advisory group.

Green chemistry is growing among chemical corporations, pushed by government regulation, landmark cases of chemical contamination and, more recently, the rise of a broader sustainability movement, said Todd Cort, the North America regional head of sustainability consulting firm Two Tomorrows.

Cort said the largest chemical companies deal mostly with businesses and aren’t necessarily as responsive to consumer demands. But companies down the supply chain can pressure their suppliers to produce more environmentally friendly chemicals.

“These companies are large enough to recognize the reputational risk from indiscriminate chemical production and also the operation benefits of not having these potential liabilities on the books,” Cort said.

Critics of point to a lack of standards for what constitutes environmentally friendly chemistry, Cort said. Some companies use old government regulations in their toxicity testing, and determining environmental impact can depend largely on context. For example, shopping bags that decay in the light won’t do much good in a landfill.

But the green chemical industry has nowhere to go but up, Cort said.

“There’s absolutely zero growth in the non-green sector,” he said. “Everything is getting more strict. All chemical production will have to slowly improve its green credentials over time.”

Elliot Njus

President’s Cancer Panel Report (National Cancer Institute) links environmental toxics to cancer; strongly endorses Green Chemistry

Thursday, May 6th, 2010

President’s Cancer Panel: Environmentally caused cancers are ‘grossly underestimated’ and ‘needlessly devastate American lives.’

“The true burden of environmentally induced cancers has been grossly underestimated,” says the President’s Cancer Panel in a strongly reported report that urges action to reduce people’s widespread exposure to carcinogens. The panel today advised President Obama “to use the power of your office to remove the carcinogens and other toxins from our food, water, and air that needlessly increase health care costs, cripple our nation’s productivity, and devastate American lives.”

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Nick.Fisher/flickr
Chemicals and contaminants might trigger cancer by various means.
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By Marla Cone
Editor in Chief
Environmental Health News
May 6, 2010

The President’s Cancer Panel on Thursday reported that “the true burden of environmentally induced cancers has been grossly underestimated” and strongly urged action to reduce people’s widespread exposure to carcinogens.

The panel advised President Obama ”to use the power of your office to remove the carcinogens and other toxins from our food, water, and air that needlessly increase health care costs, cripple our nation’s productivity, and devastate American lives.”

The 240-page report by the President’s Cancer Panel is the first to focus on environmental causes of cancer. The panel, created by an act of Congress in 1971, is charged with monitoring the multi-billion-dollar National Cancer Program and reports directly to the President every year.

Environmental exposures “do not represent a new front in the ongoing war on cancer. However, the grievous harm from this group of carcinogens has not been addressed adequately by the National Cancer Program,” the panel said in its letter to Obama that precedes the report. “The American people even before they are born are bombarded continually with myriad combinations of these dangerous exposures.”

The panel, appointed by President Bush, told President Obama that the federal government is missing the chance to protect people from cancer by reducing their exposure to carcinogens. In its letter, the panel singled out bisphenol A, a chemical used in polycarbonate plastic and can linings that is unregulated in the United States, as well as radon, formaldehyde and benzene.

“The increasing number of known or suspected environmental carcinogens compels us to action, even though we may currently lack irrefutable proof of harm.” - Dr. LaSalle D. Lefall, Jr., chair of the President’s Cancer PanelEnvironmental health scientists were pleased by the findings, saying it embraces everything that they have been saying for years.

Richard Clapp, a professor of environmental health at Boston University’s School of Public Health and one of the nation’s leading cancer epidemiologists, called the report “a call to action.”

Environmental and occupational exposures contribute to ”tens of thousands of cancer cases a year,” Clapp said. ”If we had any calamity that produced tens of thousands of deaths or serious diseases, that’s a national emergency in my view.”

The two-member panel Dr. LaSalle D. Lefall, Jr., a professor of surgery at Howard University and Margaret Kripke, a professor at University of Texas’ M.D. Anderson Cancer Center – was appointed by President Bush to three-year terms.

Lefall and Kripke concluded that action is necessary, even though in many cases there is scientific uncertainty about whether certain chemicals cause cancer. That philosophy, called the precautionary principle, is highly controversial among scientists, regulators and industry.

“The increasing number of known or suspected environmental carcinogens compels us to action, even though we may currently lack irrefutable proof of harm,” Lefall, who is chair of the panel, said in a statement.

The two panelists met with nearly 50 medical experts in late 2008 and early 2009 before writing their report to the president. Cyclist and cancer survivor Lance Armstrong previously served on the panel, but did not work on this year’s report.

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grewlike/flickr
In 2007, 69 million CT scans were performed.

The report recommends raising consumer awareness of the risks posed by chemicals in food, air, water and consumer products, bolstering research of the health effects and tightening regulation of chemicals that might cause cancer or other diseases.

They also urged doctors to use caution in prescribing CT scans and other medical imaging tests that expose patients to large amounts of radiation.  In 2007, 69 million CT scans were performed, compared with 18 million in 1993. Patients who have a chest CT scan receive a dose of radiation in the same range as survivors of the Hiroshima atomic bomb attacks who were less than half a mile from ground zero, the report says.

The panel also criticized the U.S. military, saying that “it is a major source of toxic occupational and environmental exposures that can increase cancer risk.” Examples cited include Camp Lejeune in North Carolina, where carcinogenic solvents contaminate drinking water, and Vietnam veterans with increased lymphomas, prostate cancer and other cancers from thier exposure to the herbicide Agent Orange.

Overall cancer rates and deaths have declined in the United States. Nevertheless, about 41 percent of all Americans still will be diagnosed with cancer during their lifetime, and about 21 percent will die from it, according to the National Cancer Institute’s SEER Cancer Statistics Review. In 2009 alone, about 1.5 million new cases were diagnosed.

For the past 30 years, federal agencies and institutes have estimated that environmental pollutants cause about 2 percent of all cancers and that occupational exposures may cause 4 percent.
Patients who have a chest CT scan receive a dose of radiation in the same range as survivors of the Hiroshima atomic bomb attacks who were less than half a mile from ground zero. But the panel called those estimates ”woefully out of date.” The panel criticized regulators for using them to set environmental regulations and lambasted the chemical industry for using them “to justify its claims that specific products pose little or no cancer risk.”
The report said the outdated estimates fail to take into account many newer discoveries about people’s vulnerability to chemicals. Many chemicals interact with each other, intensifying the effect, and some people have a genetic makeup or early life exposure that makes them susceptible to environmental contaminants.
“It is not known exactly what percentage of all cancers either are initiated or promoted by an environmental trigger,” the panel said in its report. “Some exposures to an environmental hazard occur as a single acute episode, but most often, individual or multiple harmful exposures take place over a period of weeks, months, year, or a lifetime.”
Boston University’s Clapp was one of the experts who spoke to the panel in 2008. ”We know enough now to act in ways that we have not done…Act on what we know,” he told them.
“There are lots of places where we can move forward here. Lots of things we can act on now,” such as military base cleanups and reducing use of CT scans, Clapp said in an interview.
Dr. Ted Schettler, director of the Science and Environmental Health Network, called the report an “integrated and comprehensive critique.” He was glad that the panel underscored that regulatory agencies should reduce exposures even when absolute proof of harm was unavailable.
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azurion2/flickr
Scientists are divided on whether there is a link between cell phones and cancer.
Also, “they recognized that exposures happen in mixtures, not in isolation” and that children are most vulnerable.
“Some people are disproportionately exposed and disproportionately vulnerable,” said Schettler, whose group was founded by environmental groups to urge the use of science to address public health issues related to the environment.
Schettler said it “took courage” for the panel to warn physicians about the cancer risk posed by CT scans, particularly for young children.

“It’s almost become routine for kids with abdominal pain to get a CT scan” to check for appendicitis, he said. Although the scans may lead to fewer unnecessary surgeries, doctors should consider the high doses of radiation. “I’m very glad this panel took that on,” Schettler said.

Another sensitive issue raised in the report was the risk of brain cancer from cell phones. Scientists are divided on whether there is a link.

Until more research is conducted, the panel recommended that people reduce their usage by making fewer and shorter calls, using hands-free devices so that the phone is not against the head and refraining from keeping a phone on a belt or in a pocket.

Even if cell phones raise the risk of cancer slightly, so many people are exposed that “it could be a large public health burden,” Schettler said.

The panel listed a variety of carcinogenic compounds that many people routinely encounter. Included are benzene and other petroleum-based pollutants in vehicle exhaust, arsenic in water supplies, chromium from plating companies, formaldehyde in kitchen cabinets and other plywood, bisphenol A in plastics and canned foods, tetrachloroethylene at dry cleaners, PCBs in fish and other foods and various pesticides.

Chemicals and contaminants might trigger cancer by a variety of means. They can damage DNA, disrupt hormones, inflame tissues, or turn genes on or off.

“Some types of cancer are increasing rapidly,” Clapp said, including thyroid, kidney and liver cancers. Others, including lung and breast cancer, have declined.

Previous reports by the President’s Cancer Panel have focused largely on treatment and more well-known causes of cancer such as diet or smoking.
The panel criticized regulators and industry for using ”woefully outdated” estimates of environmentally caused cancers to set regulations and “to justify its claims that specific products pose little or no cancer risk.”Some experts are concerned that the report might just sit on a shelf at the White House. But Clapp said the findings are so strongly stated that he is confident the report will be useful to some policymakers, legislators and groups that want tougher occupational health standards or other regulations.
“We’re not going to get any better than this,” Clapp said. “This goes farther than what I thought the President’s Cancer Panel would go. I’m pleased that they went as far as they did.”
Environmental health scientists said they hope the report raises not just the President’s awareness of environmental threats, but the public’s, since most people are unaware of the dangers.
“This report has stature,” Schettler said. “It is a report that goes directly to the president.”
PDF of the original report.